Theoretical research on shock compression properties of liquid helium at high temperature and density
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摘要: 选择高密度液氦作为研究对象,采用F.H.Ree修正的WCA状态方程和改进的分子流体微扰变分统计理论(MCRSR),并且考虑液氦体系低温量子力学效应,计算了一次和二次冲击压力在0~108 GPa、对应温度为471~32 790 K范围内的高压物态方程。在确定体系分子间相互作用时,通过实验数据拟合选取了较合理的指数6势参数。理论计算结果与实验数据吻合较好。Abstract: Considering the quantum-mechanical effect at lower temperatures, the modified Weeks-Chandler-Andersen theory and improved variational perturbation principle were used to develop the single and double shock dynamic equations of state of liquid helium at the pressures ranging from 0 to 108 GPa and the temperatures ranging from 471 to 32 790 K. The appropriate exp-6 potential parameters were obtained by fitting the experimental data based on determined interactions of molecules in liquid helium. The calculated results are in good agreement with the experimental data.
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