Effect of initial temperatures on CO2 explosion suppression
-
摘要: 将CO2充入的液化石油气中并进行点火,研究不同初始温度下CO2对多元混合气液化石油气爆炸的抑制作用。实验显示:初始温度15℃时CO2体积分数达到36%时,混合气体退出可爆范围,临界氧浓度为12.8%;初始温度50℃时CO2体积分数达到39%时,混合气体退出可爆范围,临界氧浓度为12.2%。结果表明:CO2对液化石油气爆炸的抑制效果在一定程度上要受环境温度的影响。Abstract: In this work we studied the effect of CO2 on explosion suppression for multi-component mixed gas at different initial temperatures by igniting the gas obtained from adding CO2 to the mixture of LPG and air. Our study indicates that when the volume fraction of CO2 reaches 36% at the initial temperature of 15℃, the mixed gas is beyond the explosive range and the critical volume fraction of oxygen is 12.8%; when the volume fraction of CO2 reaches 39% at the initial temperature of 50℃, the mixed gas is beyond the explosive range, and the critical volume fraction oxygen is 12.2%. The result shows that the effect of CO2 on the LPG suppression explosion is influenced by temperature to a certain extent.
-
Key words:
- mechanics of explosion /
- explosion suppresion /
- temperature /
- LPG /
- CO2
-
表 1 初温15℃时CO2抑爆体积分数
Table 1. Volume fractions of CO2 explosion suppresion at initial temperature of 15℃
No. φ1/% φ2/% φ3/% 1 2.2 0 20.5 2 3.0 36.0 12.8 3 4.0 33.0 13.2 4 5.0 29.0 13.9 5 6.0 26.0 14.3 6 7.0 20.0 15.3 7 8.0 13.0 16.6 8 9.0 8.0 17.4 9 10.0 5.0 17.9 10 10.8 0 18.7 表 2 初温50℃时CO2抑爆体积分数
Table 2. Volume fractions of CO2 explosion suppresion at initial temperature of 50℃
No. φ1/% φ2/% φ3/% 1 2.0 0 20.6 2 3.0 39.0 12.2 3 4.0 34.0 13.0 4 5.0 31.0 13.4 5 6.0 28.0 13.9 6 7.0 21.0 15.1 7 8.0 16.0 16.0 8 9.0 10.0 17.0 9 10.0 7.0 17.4 10 11.9 0 18.5 -
[1] 钱海林, 王志荣, 蒋军成.N2/CO2混合气体对甲烷爆炸的影响[J].爆炸与冲击, 2012, 32(4):445-448. doi: 10.3969/j.issn.1001-1455.2012.04.016Qian Hailin, Wang Zhirong, Jiang Juncheng. Influence of N2/CO2 mixture on methane explosion[J]. Explosion and Shock Waves, 2012, 32(4):445-448. doi: 10.3969/j.issn.1001-1455.2012.04.016 [2] 张景林, 肖林, 寇丽平, 等.气体爆炸抑制技术研究[J].兵工学报, 2000, 21(8):261-263. http://d.old.wanfangdata.com.cn/Periodical/bgxb200003018Zhang Jinglin, Xiao Lin, Kou Liping, et al. A study on the suppression of gas-explosion hazards[J]. Acta Armamentarii, 2000, 21(8):261-263. http://d.old.wanfangdata.com.cn/Periodical/bgxb200003018 [3] 马长安, 任建平.矿井可燃气体爆炸及抑制研究[J].煤, 2006, 15(2):22-23. http://d.old.wanfangdata.com.cn/Periodical/m200602012Ma Changan, Ren Jianping. Study of explosion control inside and outside explosion-proof cabinet[J]. Coal, 2006, 15(2):22-23. http://d.old.wanfangdata.com.cn/Periodical/m200602012 [4] 邱雁, 高广伟, 罗海珠.充注惰气抑制矿井火区瓦斯爆炸机理[J].煤矿安全, 2003, 34(2):8-11. http://d.old.wanfangdata.com.cn/Periodical/mkaq200302005Qiu Yan, Gao Guangwei, Luo Haizhu. Mechanism of pumping inert gas into mine fire area for inhibition of methane explosion[J]. Safety in Coal Mines, 2003, 34(2):8-11. http://d.old.wanfangdata.com.cn/Periodical/mkaq200302005 [5] 王华, 葛岭梅, 邓军.惰性气体抑制矿井瓦斯爆炸的实验研究[J].矿业安全环保, 2008, 35(1):4-7. http://d.old.wanfangdata.com.cn/Periodical/kyaqyhb200801002Wang Hua, Ge Lingmei, Deng Jun. Experimental study of using inert gas to suppress mine gas explosion[J]. Mining Safety & Environmental Protection, 2008, 35(1):4-7. http://d.old.wanfangdata.com.cn/Periodical/kyaqyhb200801002 [6] 张辉, 王威, 邓军.矿井瓦斯爆炸纳米粉体控制技术的探讨[J].煤矿现代化, 2005(2):43-44. doi: 10.3969/j.issn.1009-0797.2005.02.028Zhang Hui, Wang Wei, Deng Jun. Discussion on control technique of nanometer powder using in mine gas explosion[J]. Coal Mine Modernization, 2005(2):43-44. doi: 10.3969/j.issn.1009-0797.2005.02.028 [7] 陈晓坤, 林滢, 罗振敏, 等.水系抑制剂控制瓦斯爆炸的实验研究[J].煤炭学报, 2006, 31(5):603-606. doi: 10.3321/j.issn:0253-9993.2006.05.012Chen Xiaokun, Lin Ying, Luo Zhenmin, et al. Experimental study on controlling gas explosion by water-depressant[J]. Journal of China Coal Society, 2006, 31(5):603-606. doi: 10.3321/j.issn:0253-9993.2006.05.012 [8] 刘晅亚, 陆守香, 秦俊.水雾抑制气体爆炸火焰传播的实验研究[J].中国安全科学学报, 2003, 13(8):72-77. http://d.old.wanfangdata.com.cn/Periodical/zgaqkxxb200308019Liu Xuanya, Lu Shouxiang, Qin Jun. Experimental study on inhibiting the gas explosion flame by water spray[J]. China Safety Science Journal, 2003, 13(8):72-77. http://d.old.wanfangdata.com.cn/Periodical/zgaqkxxb200308019 [9] Benedetto A D, Sarli V D, Salzano E, et al. Explosion behavior of CH4/O2/N2/CO2 and H2/O2/N2/CO2 mixtures[J]. International Journal of Hydrogen Energy, 2009, 34(16):6970-6978. doi: 10.1016/j.ijhydene.2009.05.120 [10] Razus D, Movileanu C, Brinzea V, et al. Closed vessel combustion of propylene-air mixtures in the presence of exhaust gas[J]. Fuel, 2007, 86(12):1865-1872. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=62fa8f5dbf9662f98c94690898605564 [11] 郑远攀, 景国勋, 张亚丽.CH4/CO2混合气体爆燃特性研究进展[J].爆炸与冲击, 2012, 32(2):203-209. doi: 10.3969/j.issn.1001-1455.2012.02.015Zheng Yuanpan, Jing Guoxun, Zhang Yali. A review of explosion characteristics of methane and carbon dioxide gas mixtures[J]. Explosion and Shock Waves, 2012, 32(2):203-209. doi: 10.3969/j.issn.1001-1455.2012.02.015 [12] 吴志远, 胡双启, 谭迎新.氮气对人工煤气抑爆技术的实验研究[J].陕西科技大学学报, 2009, 27(2):104-107. doi: 10.3969/j.issn.1000-5811.2009.02.026Wu Zhiyuan, Hu Shuangqi, Tan Yingxin. A study on the suppressing technology of explosion of the artificial coal gases[J]. Journal of Shanxi University of Science & Technology, 2009, 27(2):104-107. doi: 10.3969/j.issn.1000-5811.2009.02.026 [13] GB/T12474-2008.空气中可燃气体爆炸极限测定方法[S].北京: 中国标准出版社. [14] 田贯三, 于畅, 李兴泉.燃气爆炸极限计算方法的研究[J].煤气与热力, 2006, 26(3):29-33. doi: 10.3969/j.issn.1000-4416.2006.03.010Tian Guansan, Yu Chang, Li Xingquan. Study on calculation method of gas explosion limits[J]. Gas & Heat, 2006, 26(3):29-33. doi: 10.3969/j.issn.1000-4416.2006.03.010 [15] 杜文峰.消防燃烧学[M].北京:警官教育出版社, 1996.