计算CHNO和CHNOAl炸药爆速的一种新方法

杨慕天; 郑波

doi:10.11883/bzycj-2016-0140

计算CHNO和CHNOAl炸药爆速的一种新方法

doi: 10.11883/bzycj-2016-0140

杨慕天,
郑波^,

北京理工大学爆炸科学与技术国家重点实验室, 北京 100081

详细信息

作者简介:
杨慕天(1992—), 男, 硕士研究生

通讯作者:
郑波, zhengbo@bit.edu.cn

中图分类号: O381
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- 被引次数: 0
出版历程
- 收稿日期: 2016-05-18
- 修回日期: 2016-06-07
- 刊出日期: 2018-01-25

A new method for calculating the detonation velocity of CHNO and CHNOAl explosives

YANG Mutian,
ZHENG Bo^,

State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China

摘要

摘要: 基于理想混合炸药模型的概念，提出一种计算混合炸药爆速的新方法，并构造空气和铝粉与炸药组分相关的特征爆速关系式。对装药密度大于最大理论密度85%的26种CHNO类混合炸药、13种CNNO类单质炸药、25种含铝炸药进行计算，爆速的计算值与实验值吻合较好，平均相对误差为0.01%，相关系数为0.961 5。通过数据分析，新方法优于Urizar方法和Kamlet方法。新方法是一种计算CHNO类和CHNOAl炸药爆速的可靠方法，对新型混合炸药的研究具有一定指导意义。
- CHNO类炸药 /
- CHNOAl炸药 /
- Kamlet方法 /
- Urizar方法
Abstract: In this work we put forward a new method for calculating the detonation velocity of composite explosive based on the concept of the ideal composite explosive model, and constructed the characteristic detonation velocity equation of air and aluminum with explosive composition. Using this method, we performed calculation of the detonation velocity for 26 mixed CHNO explosives, 13 pure CHNO explosives, and 25 aluminized explosives, all of whose maximum theoretical charge density is more than 85%. The results showed that the calculated detonation velocities were in good agreement with the experimental values. The average relative error was 0.01% and the square of the correlation coefficient is 0.9615. Compared with the commonly adopted methods such as Kamlet and Urizar, the new method was more accurate. The new method not only provides a new way to calculate the detonation velocity of CHNO explosives and CHNOAl explosives, but may also serve as reference for the study of new composite explosives.
- CHNO explosives /
- CHNOAl explosives /
- Kamlet method /
- Urizar method

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图 1 混合炸药分离示意图

Figure 1. Schematic of composite explosive separation

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表 1 CHNO类混合炸药爆速的实验与计算对比

Table 1. Comparison between experimental and calculated data of mixed CHNO explosives detonation velocity

编号	炸药配比	ρ₀/(g·cm^-3)	D/(km·s^-1)			D/(km·s^-1)			D/(km·s^-1)
编号	炸药配比	ρ₀/(g·cm^-3)	实验^[9]	计算	ε/%	实验^[9]	Kamlet	ε/%	实验^[9]	Urizar	ε/%
1	50RDX/50TNT	1.627	7.600	7.570	-0.34	7.600	7.460	-1.84	7.600	7.584	-0.21
2	60RDX/40TNT	1.715	7.890	7.904	0.18	7.890	7.902	0.15	7.890	7.993	1.31
3	64RDX/36TNT	1.713	8.030	7.972	-0.73	8.030	7.942	-1.10	8.030	8.039	0.11
4	65RDX/35TNT	1.715	8.060	7.992	-0.85	8.060	7.961	-1.23	8.060	8.059	-0.03
5	75RDX/25TNT	1.648	7.952	7.974	0.28	7.952	7.823	-1.16	7.952	7.965	0.16
6	77RDX/23TNT	1.743	8.252	8.246	-0.08	8.252	8.212	-0.48	8.252	8.303	0.62
7	78RDX/22TNT	1.755	8.306	8.276	-0.37	8.306	8.271	-0.43	8.306	8.356	0.60
8	42.7RDX/57.3TNT	1.700	7.500	7.603	1.38	7.500	7.641	1.88	7.500	7.719	2.92
9	35PETN/65TNT	1.668	7.358	7.353	-0.07	7.358	7.331	-0.37	7.358	7.523	2.24
10	40PETN/60TNT	1.673	7.303	7.413	1.50	7.303	7.391	1.21	7.303	7.605	4.14
11	45PETN/55TNT	1.677	7.420	7.474	0.73	7.420	7.448	0.38	7.420	7.684	3.56
12	50PETN/50TNT	1.682	7.662	7.537	-1.63	7.662	7.510	-1.99	7.662	7.765	1.35
13	50PETN/50TNT	1.660	7.530	7.514	-0.21	7.530	7.431	-1.32	7.530	7.696	2.20
14	60PETN/40TNT	1.650	7.730	7.608	-1.58	7.730	7.480	-3.23	7.730	7.792	0.81
15	60PETN/40TNT	1.626	7.340	7.547	2.82	7.340	7.393	0.73	7.340	7.715	5.11
16	25PETN/75TNT	1.623	7.250	7.198	-0.71	7.250	7.090	-2.21	7.250	7.251	0.02
17	20PETN/80TNT	1.603	7.200	7.115	-1.17	7.200	6.979	-3.06	7.200	7.124	-1.05
18	20PETN/80TNT	1.600	7.200	7.109	-1.26	7.200	6.969	-3.21	7.200	7.115	-1.18
19	10PETN/90TNT	1.624	7.100	7.056	-0.62	7.100	6.968	-1.87	7.100	7.051	-0.69
20	60CE/40TNT	1.620	7.330	7.337	0.09	7.330	7.174	-2.12	7.330	7.225	-1.43
21	60CE/40TNT	1.639	7.390	7.375	-0.20	7.390	7.241	-2.02	7.390	7.282	-1.46
22	65CE/35TNT	1.679	7.540	7.458	-1.09	7.540	7.407	-1.76	7.540	7.430	-1.45
23	76.3HMX/23.7TNT	1.809	8.452	8.437	-0.17	8.452	8.450	-0.03	8.452	8.506	0.64
24	70HMX/30TNT	1.800	8.377	8.283	-1.12	8.377	8.337	-0.48	8.377	8.394	0.20
25	75HMX/25TNT	1.810	8.480	8.407	-0.86	8.480	8.437	-0.50	8.480	8.492	0.15
26	50ENDA/50TNT	1.530	7.180	7.294	1.59	7.180	7.142	-0.53	7.180	7.179	-0.01

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表 2 CHNO类单质炸药爆速的实验与计算对比

Table 2. Comparison between experimental and calculated data of pure CHNO explosives detonation velocity

编号	炸药	ρ₀/(g·cm^-3)	D/(km·s^-1)			D/(km·s^-1)
编号	炸药	ρ₀/(g·cm^-3)	实验^[10]	计算	ε/%	实验^[10]	Kamlet	ε/%
1	RDX	1.80	8.750	8.794	0.51	8.750	8.786	0.42
2	RDX	1.77	8.700	8.764	0.74	8.700	8.684	-0.19
3	RDX	1.72	8.460	8.648	2.22	8.460	8.513	0.62
4	RDX	1.66	8.240	8.388	1.79	8.240	8.308	0.82
5	RDX	1.60	8.130	7.988	-1.75	8.130	8.102	-0.34
6	HMX	1.89	9.110	9.145	0.38	9.110	9.086	-0.26
7	PETN	1.76	8.270	8.279	0.10	8.270	8.663	4.75
8	PETN	1.70	8.070	8.208	1.71	8.070	8.457	4.80
9	PETN	1.60	7.750	7.812	0.80	7.750	8.115	4.71
10	TETRYL	1.71	7.850	7.655	-2.49	7.850	7.714	-1.74
11	TETRYL	1.68	7.500	7.625	1.67	7.500	7.620	1.60
12	TETRYL	1.61	7.580	7.443	-1.80	7.580	7.402	-2.34
13	TETRYL	1.73	7.720	7.660	-0.78	7.720	7.776	0.72

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表 3 含铝炸药爆速的实验与计算对比

Table 3. Comparison between experimental and calculated data of aluminized explosives detonation velocity

编号	炸药配比	ρ₀/(g·cm^-3)	D/(km·s^-1)			D/(km·s^-1)
编号	炸药配比	ρ₀/(g·cm^-3)	实验^[11]	计算	ε/%	实验^[11]	Urizar	ε/%
1	90HMX/10Al	1.76	8.300	8.260	-0.48	8.300	8.193	-1.29
2	80HMX/20Al	1.82	8.300	8.091	-2.51	8.300	8.053	-2.98
3	70HMX/30Al	1.86	8.000	7.833	-2.08	8.000	7.820	-2.24
4	60HMX/40Al	1.94	7.700	7.624	-0.98	7.700	7.700	0
5	90RDX/10Al	1.68	8.030	7.968	-0.77	8.030	7.898	-1.65
6	80RDX/20Al	1.73	7.770	7.755	-0.19	7.770	7.737	-0.43
7	70RDX/30Al	1.79	7.580	7.622	0.56	7.580	7.590	0.13
8	60RDX/40Al	1.84	7.200	7.261	0.85	7.200	7.387	2.59
9	50RDX/50Al	1.89	6.810	6.826	0.23	6.810	7.163	5.18
10	90TNETB/10Al	1.75	8.120	8.024	-1.18	8.120	7.864	-3.16
11	80TNETB/20Al	1.82	7.990	7.921	-0.87	7.990	7.784	-2.58
12	70TNETB/30Al	1.88	7.840	7.817	-0.30	7.840	7.645	-2.49
13	89.4TNT/10.6Al	1.72	7.050	6.938	-1.58	7.050	6.959	-1.29
14	78.3TNT/21.7Al	1.80	7.050	6.934	-1.65	7.050	6.946	-1.47
15	67.8TNT/32.2Al	1.89	7.050	6.939	-1.57	7.050	6.943	-1.36
16	42RDX/40TNT/18Al	1.81	7.500	7.577	1.03	7.500	7.595	1.27
17	44RDX/32.2TNT/19.8Al/4wax	1.80	7.530	7.602	0.95	7.530	7.708	2.36
18	37.4RDX/27.8TNT/30.8Al/4wax	1.88	7.300	7.517	2.97	7.300	7.618	4.36
19	40RDX/38TNT/17Al/5wax	1.72	7.220	7.373	2.13	7.220	7.484	3.65
20	31RDX/29TNT/35Al/5wax	1.81	6.920	7.056	1.97	6.920	7.249	4.75
21	45RDX/30TNT/20Al/5wax	1.71	7.190	7.291	1.41	7.190	7.440	3.47
22	80TNT/20Al	1.72	6.700	6.875	2.62	6.700	6.743	0.65
23	41RDX/41TNT/18Al	1.81	7.530	7.561	0.41	7.530	7.582	0.69
24	42.1RDX/42.1TNT/15Al/0.8wax	1.75	7.490	7.531	0.55	7.490	7.519	0.39
25	42.1RDX/42.1TNT/15AL/0.8wax	1.75	7.510	7.535	0.33	7.510	7.526	0.22

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表 4 不同计算方法的精度对比

Table 4. Comparison of calculated accuracy between different methods

炸药	计算方法	误差范围/%				ε/%	ε_max/%	R²
炸药	计算方法	\|ε\|≤1	1＜\|ε\|≤2	2＜\|ε\|≤3	\|ε\|＞3	ε/%	ε_max/%	R²
CHNO混合炸药	本文方法	16	9	1	0	-0.17	2.82	0.967 2
CHNO混合炸药	Urizar方法	10	10	3	3	-1.04	-3.23	0.957 9
CHNO混合炸药	Kamlet方法	13	7	3	3	0.72	5.11	0.918 6
CHNO单质炸药	本文方法	6	5	2	0	0.24	-2.49	0.953 6
CHNO单质炸药	Kamlet方法	7	2	1	3	1.04	4.80	0.865 7
含铝炸药	本文方法	13	7	5	0	0.07	2.97	0.949 6
含铝炸药	Urizar方法	7	6	6	6	0.35	5.18	0.851 9

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参考文献(12)

[1]	MADER C L. Numerical modeling of explosives and propellants[M]. Boca Raton: CRC Press, 2008:31-63.
[2]	陈朗, 龙新平, 冯长根, 等.含铝炸药爆轰[M].北京:国防工业出版社, 2004:30-42.
[3]	KAMIET M J, JACOBS S J. Chemistry of detonations Ⅰ: A simple method for calculating detonation properties of C-H-N-O explosives[J]. Journal of Chemical Physics, 1968, 48(1): 23-25. doi: 10.1063/1.1667908
[4]	李金山.计算含能材料爆速的一种新方法[J].火炸药学报, 1994, 17(3):28-32. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=hncl200002012 LI Jinshan. A new method for calculating the detonation velocity of energetic materials[J]. Explosives and Propellants, 1994, 17(3):28-32. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=hncl200002012
[5]	王克强, 孙献忠.理想混合炸药模型的提出及其应用[J].火炸药学报, 2002, 25(1):51-53. http://www.cqvip.com/QK/90400B/200201/6085809.html WANG Keqiang, SUN Xianzhong. An ideal composite explosive model proposed and its application[J]. Explosives and Propellants, 2002, 25(1):51-53. http://www.cqvip.com/QK/90400B/200201/6085809.html
[6]	桑德勒S I. 化学与工程热力学[M]. 吴志高, 译. 北京: 化学工业出版社, 1985: 173-460.
[7]	孙业斌, 惠君明, 曹欣茂.军用混合炸药[M].北京:兵器工业出版社, 1995:82-83.
[8]	孙业斌.爆炸作用与装药设计[M].北京:国防工业出版社, 1987.
[9]	郭金波.理想混合炸药爆速的计算[J].洛阳师范学院学报, 2003, 22(2):41-44. http://edu.wanfangdata.com.cn/Periodical/Detail/lysfxyxb200302014 GUO Jinbo. The calculation of the detonation velocity of an ideal composite explosive[J]. Journal of Luoyang Teachers College, 2003, 22(2):41-44. http://edu.wanfangdata.com.cn/Periodical/Detail/lysfxyxb200302014
[10]	KESHAVARZ M H. A simple approach for determining detonation velocity of high explosive at any loading density[J]. Journal of Hazardous Materials, 2005, 121(1/2/3):31-36. https://www.sciencedirect.com/science/article/pii/S0304389405000658
[11]	KESHAVARZ M H. Predicting maximum attainable detonation velocity of CHNOF and aluminized explosives[J]. Propellants Explosives Pyrotechnics, 2012, 37(4):489-497. doi: 10.1002/prep.v37.4
[12]	韩早, 王伯良.混合炸药爆速预报的新方法[J].爆炸与冲击, 2014, 34(4):421-426. doi: 10.11883/1001-1455(2014)04-0421-06 HAN Zao, WANG Boliang. The new method for predicting detonation velocity of composite explosive[J]. Explosion and Shock Waves, 2014, 34(4):421-426. doi: 10.11883/1001-1455(2014)04-0421-06