Zr基非晶合金破片冲击破碎反应机制研究

张云峰; 方龙; 魏欣; 徐畅; 随亚光; 施冬梅

doi:10.11883/bzycj-2022-0187

Zr基非晶合金破片冲击破碎反应机制研究

doi: 10.11883/bzycj-2022-0187

张云峰^1,,
方龙^1, ,,
魏欣¹,
徐畅¹,
随亚光¹,
施冬梅²

1.
西北核技术研究所，陕西西安 710000
2.
陆军工程大学石家庄校区，河北石家庄 050000

详细信息

作者简介:
张云峰（1990－　），男，博士，助理研究员，1193954881@qq.com

通讯作者:
方　龙（1988－　），男，博士，助理研究员，751173072@ qq.com

中图分类号: O385; TJ410
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- 被引次数: 0
出版历程
- 收稿日期: 2022-05-05
- 修回日期: 2022-09-04
- 网络出版日期: 2022-09-14
- 刊出日期: 2023-01-05

Research on mechanism of shock fragmentation reaction of Zr-based bulk metallic glass fragment

1.
Northwest Institute of Nuclear Technology, Xi’an 710000, Shaanxi, China
2.
Shijiazhuang Campus of Army Engineering University, Shijiazhuang 050000, Hebei, China

摘要

摘要: 为研究Zr基非晶合金破片的冲击破碎反应机制，进行了准密封箱冲击超压实验，测试了破片的碎片粒度，分析了碎片尺寸分布关系，并对不同粒径尺度的碎片进行了X射线衍射分析。实验结果表明，材料在冲击加载下的反应程度随着撞击速度的升高而增大；碎片分布符合分段式幂次律分布规律；材料冲击诱发的化学反应主要为Zr元素与空气中氧气的燃烧，其主要反应产物为ZrO₂。基于冲击升温-碎片分布-碎片燃烧的冲击破碎反应理论模型能较好地解释冲击作用下Zr基非晶合金破片的反应规律，理论计算与实验结果吻合度较高。
- Zr基非晶合金 /
- 冲击 /
- 破碎 /
- 反应机制
Abstract: Zr-based bulk metallic glasses are novel class of functional materials that comprehensively use chemical energy and kinetic energy to improve the damage effect of warhead. To investigate the mechanism of shock fragmentation reaction of Zr-based bulk metallic glass fragments, quasi-sealed venting chamber was used to measure the released energy of Zr_62.5Nb₃Cu_14.5Ni₁₄Al₆ bulk metallic glass fragments under impact conditions. The fragments were driven by a 14.5 mm ballistic gun, with various levels of velocity, to impact the sealed chamber covered by 0.5 mm thick steel plates. High-speed camera was used to record the shock-fragmentation-reaction process through an observational window. The pressure in the chamber was measured by two pressure sensors installed in different positions on the inner wall of the chamber. The particle size of the fragment debris was measured by laser diffraction method and weighting method. And the debris with different particle sizes was analyzed by X-ray diffraction. According to one dimensional shock wave theory, the impact temperature of Zr-based bulk metallic glass was derived. Combined with the impact temperature, the fragment debris distribution model and metal particle ignition model, the shock-fragmentation-reaction theoretical model was developed to quickly calculate the extent of reaction of Zr-based bulk metallic glass fragments. The experiments results show that the reaction depth of material under impact loading increases with the increase of impact velocity. The distribution of debris conforms to the piecewise power law, and the size distribution of debris was fitted. The main chemical reaction induced by material impacting is the combustion of Zr and O₂ in the air, and the main reaction product is ZrO₂. Theoretical analysis results show that the shock-fragmentation-reaction theoretical model based on impact heating, debris distribution and debris combustion can explain the reaction law of Zr-based bulk metallic glass under impact loading well. And the theoretical calculation is in good agreement with the experimental results.
- Zr-based bulk metallic glass /
- impact /
- fragmentation /
- reaction mechanism

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图 1 准密封箱冲击超压实验布置

Figure 1. Experimental layout of quasi-sealed chamber shock overpressure test

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图 2 破片飞行过程高速摄影图像

Figure 2. High-speed photograph of fragment flight

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图 3 破片冲击破碎反应过程高速摄影图像

Figure 3. High-speed photographs of process for reaction of fragments

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图 4 实测压力曲线与准静态压力曲线

Figure 4. Actual pressure and quasi-static pressure curves

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图 5 准静态压力-时间曲线

Figure 5. Quasi-static pressure-time curves

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图 6 碎片粒度分布测试结果

Figure 6. Test results of debris size distribution

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图 7 碎片粒度分布模型

Figure 7. Models of debris size distribution

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图 8 碎片XRD分析结果

Figure 8. Results of XRD analysis of debris

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图 9 反应程度-撞击速度曲线

Figure 9. Curve of extent of reaction vs. impacting velocity

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图 10 Zr_62.5Nb₃Cu_14.5Ni₁₄Al₆非晶合金的冲击压力、温度与撞击速度的关系

Figure 10. Relationships among shock pressure, shock temperature and impact velocity of Zr_62.5Nb₃Cu_14.5Ni₁₄Al₆ bulk metallic glass

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图 11 Zr碎片着火温度的尺寸效应

Figure 11. Size effect of ignition temperature for Zr fragments

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图 12 反应深度与冲击速度、冲击压力关系的实验与理论计算结果对比

Figure 12. Comparison between experimental results and theoretical results of relationships among reaction extent, impact velocity and shock pressure

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表 1 超压峰值实验数据

Table 1. Experimental data of overpressure peak data

试验编号	v/(m·s⁻¹)	m/g	$ {{\Delta }}p $/MPa
1	552	3.43	0.019
2	723	3.4	0.033
3	834	3.42	0.042
4	1105	3.49	0.058
5	1152	3.42	0.069
6	1242	3.36	0.105
7	1406	3.41	0.124
8	1485	3.47	0.151

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表 2 实验数据及计算结果

Table 2. Results of calculation and experimental data

实验	v/(m·s⁻¹)	$ {{\Delta }}{E_{\text{C}}} $/kJ	E_k/kJ	$ {{\Delta }}Q $/kJ	Q_c/kJ	y/%
1	552	1.67	0.16	1.52	29.32	5.17
2	723	2.90	0.27	2.64	29.06	9.08
3	834	3.70	0.36	3.34	29.23	11.42
4	1 105	5.10	0.64	4.47	29.83	14.97
5	1 152	6.07	0.68	5.39	29.23	18.44
6	1 242	9.24	0.78	8.46	28.72	29.47
7	1 406	10.91	1.01	9.90	29.15	33.97
8	1 485	13.29	1.15	12.24	29.66	40.93

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参考文献(17)

[1]	LUO P G, WANG Z C, JIANG C L, et al. Experimental study on impact-initiated characters of W/Zr energetic fragments [J]. Materials and Design, 2015, 84: 72–78. DOI: 10.1016/j.matdes.2015.06.107.
[2]	WANG C T, HE Y, JI C, et al. Investigation on shock-induced reaction characteristics of a Zr-based metallic glass [J]. Intermetallics, 2018, 93: 383–388. DOI: 10.1016/j.intermet.2017.11.004.
[3]	WEI H Y, YOO C S. Dynamic responses of reactive metallic structures under thermal and mechanical ignitions [J]. Journal of Materials Research, 2012, 27(21): 2705–2717. DOI: 10.1557/jmr.2012.302.
[4]	WEI H Y, YOO C S. Dynamic structural and chemical responses of energetic solids [J]. MRS Online Proceedings Library (OPL), 2012, 1405: 62–71. DOI: 10.1557/opl.2012.59.
[5]	JI C, HE Y, WANG C T, et al. Effect of dynamic fragmentation on the reaction characteristics of a Zr-based metallic glass [J]. Journal of Non-Crystalline Solids, 2019, 515: 149–156. DOI: 10.1016/j.jnoncrysol.2019.04.022.
[6]	GRADY D E. Fragment size distributions from the dynamic fragmentation of brittle solids [J]. International Journal of Impact Engineering, 2008, 35(12): 1557–1562. DOI: 10.1016/j.ijimpeng.2008.07.042.
[7]	GRADY D E. Length scales and size distributions in dynamic fragmentation [J]. International Journal of Fracture, 2010, 163(1/2): 85–99. DOI: 10.1007/s10704-009-9418-4.
[8]	ZHANG X F, SHI A S, QIAO L, et al. Experimental study on impact-initiated characters of multifunctional energetic structural materials [J]. Journal of Applied Physics, 2013, 113(8): 083508. DOI: 10.1063/1.4793281.
[9]	谭华. 实验冲击波物理导引 [M]. 北京: 国防工业出版社, 2007: 4–87. TAN H. Introduction to experimental shock-wave physics [M]. Beijing: National Defense Industry Press, 2007: 4–87.
[10]	ZHANG X F, SHI A S, ZHANG J, et al. Thermochemical modeling of temperature controlled shock-induced chemical reactions in multifunctional energetic structural materials under shock compression [J]. Journal of Applied Physics, 2012, 111(12): 123501. DOI: 10.1063/1.4729048.
[11]	张云峰. Zr基非晶合金破片特性及毁伤机理研究 [D]. 石家庄: 陆军工程大学, 2020: 29–84.
[12]	MOHAN S, TRUNOV M A, DREIZIN E L. Heating and ignition of metal particles in the transition heat transfer regime [J]. Journal of Heat Transfer, 2008, 130(10): 104505. DOI: 10.1115/1.2945881.
[13]	PHUOC T X, CHEN R H. Modeling the effect of particle size on the activation energy and ignition temperature of metallic nanoparticles [J]. Combustion and Flame, 2012, 159(1): 416–419. DOI: 10.1016/j.combustflame.2011.07.003.
[14]	MOHAN S, TRUNOV M A, DREIZIN E L. On possibility of vapor-phase combustion for fine aluminum particles [J]. Combustion and Flame, 2009, 156(11): 2213–2216. DOI: 10.1016/j.combustflame.2009.08.007.
[15]	HUANG Y, RISHA G A, YANG V, et al. Effect of particle size on combustion of aluminum particle dust in air [J]. Combustion and Flame, 2009, 156(1): 5–13. DOI: 10.1016/j.combustflame.2008.07.018.
[16]	张云峰, 罗兴柏, 李晨, 等. 锆、铝颗粒活化能尺寸效应的理论模型 [J]. 稀有金属材料与工程, 2020, 49(12): 4097–4102. ZHANG Y F, LUO X B, LI C, et al. Analytical model for size effect of activation energy of zirconium and aluminum particles [J]. Rare Metal Materials and Engineering, 2020, 49(12): 4097–4102.
[17]	MAGLIA F, ANSELMI-TAMBURINI U, GENNARI S, et al. Dynamic behaviour and chemical mechanism in the self-propagating high-temperature reaction between Zr powders and oxygen gas [J]. Physical Chemistry Chemical Physics, 2001, 3(3): 489–496. DOI: 10.1039/B005678M.