Wu Qiu-jie, Tan Liu, Xu Sen, Liu Da-bin. Effects of typical additives on the anti-explosion performance of ammonium nitrate[J]. Explosion And Shock Waves, 2015, 35(6): 825-831. doi: 10.11883/1001-1455(2015)06-0825-07
Citation: Wu Qiu-jie, Tan Liu, Xu Sen, Liu Da-bin. Effects of typical additives on the anti-explosion performance of ammonium nitrate[J]. Explosion And Shock Waves, 2015, 35(6): 825-831. doi: 10.11883/1001-1455(2015)06-0825-07

Effects of typical additives on the anti-explosion performance of ammonium nitrate

doi: 10.11883/1001-1455(2015)06-0825-07
  • Received Date: 2014-05-13
  • Rev Recd Date: 2014-07-14
  • Publish Date: 2015-12-10
  • Several typical additives were selected and added to ammonium nitrate (AN), and UN gap test was conducted to study the effects of the added amount and mixing method on the anti-explosion performance of AN. Experimental results obtained indicate improvement of certain anti-explosion performance on AN for potassium chlorate (KCl), sodium chloride (NaCl) and monoammonium phosphate (NH4H2PO4) added. When the added amount of KCl is 20% by mechanical mixing or 15% by solution mixing, that of NaCl is 35% or 15%, and that of NH4H2PO4 is 25% or 30%, AN ceases to propagate detonation. As to the chloride additives, solution mixing can mix AN and additives more evenly, thus obtaining better anti-explosion performance. In addition, as the acidity of NH4H2PO4 added to AN by solution mixing could accelerate thermal decomposition, better anti-explosion performance for that is also achieved by mechanical mixing.
  • [1]
    戴志谦, 周国成, 李天文, 等.添加剂对硝酸铵热稳定性及爆炸性的影响[J].上海化工, 2008, 33(3): 11-15. http://d.wanfangdata.com.cn/periodical/shhg200803004

    Dai Zhi-qian, Zhou Guo-cheng, Li Tian-wen, et al. The effects of additives on thermal stability and explosivity of ammonium Nitrate[J]. Shanghai Chemical Industry, 2008, 33(3): 11-15. http://d.wanfangdata.com.cn/periodical/shhg200803004
    [2]
    吕春绪, 刘祖亮, 倪欧琪.工业炸药[M].北京: 兵器工业出版社, 1994: 218.
    [3]
    徐志祥, 胡毅亭, 刘大斌, 等.铁离子对硝酸铵热行为的影响[J].火炸药学报, 2010, 33(3): 34-37; 50. http://www.cnki.com.cn/Article/CJFDTotal-BGXB201003010.htm

    Xu Zhi-xiang, Hu Yi-ting, Liu Da-bin, et al. Influence of iron ion on thermal behavior of ammonium nitrate[J]. Chinese Journal of Explosives & Propellants, 2010, 33(3): 34-37; 50. http://www.cnki.com.cn/Article/CJFDTotal-BGXB201003010.htm
    [4]
    Oxley J C, Smith James L, Rogers Evan, et al. Ammonium nitrate: Thermal stability and explosivity modifiers[J]. Thermochimica Acta, 2002, 384: 23-45. https://www.sciencedirect.com/science/article/pii/S0040603101007754
    [5]
    Keenan A G, Dimitriades B. Mechanism for the chloride-catalyzed thermal decomposition of ammonium nitrate[J]. The Journal of Chemical Physics, 1962, 37(8): 1583-1586. doi: 10.1063/1.1733343
    [6]
    Keenan A G, Notz K, Franco N B. Synergistic catalysis of ammonium nitrate decomposition[J]. Journal of the American Chemical Society, 1969, 91: 3168-3171. doi: 10.1021/ja01040a011
    [7]
    李新蕊, 古积博.法国硝酸铵化肥工厂爆炸事故介绍及调查[J].爆破器材, 2003, 32(4): 31-36. http://d.wanfangdata.com.cn/Periodical/bpqc200304008

    Li Xin-rui, Koseki H. The accident and its investigations of the ammonium nitrate explosion in Toulouse's France[J]. Explosive Materials, 2003, 32(4): 31-36. http://d.wanfangdata.com.cn/Periodical/bpqc200304008
    [8]
    United Nations. Recommendations on the transport of dangerous goods. Model regulations[S]. New York and Geneva: UN, 2003.
    [9]
    唐双凌, 刘祖亮, 朱广军, 等.添加剂对硝酸铵爆轰安全性和热稳定性的影响[J].化肥工业, 2003, 30(4): 28-29; 32. http://d.wanfangdata.com.cn/Periodical/hfgy200304009

    Tang Shuang-ling, Liu Zu-liang, Zhu Guang-jun, et al. Effect of additives on detonation safety and heat stability of ammonium nitrate[J]. Chemical Fertilizer Industry, 2003, 30(4): 28-29; 32. http://d.wanfangdata.com.cn/Periodical/hfgy200304009
    [10]
    张为鹏, 张亦安, 赵省向.杂质的影响及硝铵生产中爆炸事故的预防[J].化肥工业, 1999, 27(1): 40-42. http://d.wanfangdata.com.cn/Periodical/hfgy200001011

    Zhang Wei-peng, Zhang Yi-an, Zhao Sheng-xiang. Effect of impurities and prevention of explosion accident in production of ammonium nitrate[J]. Chemical Fertilizer Industry, 1999, 27(1): 40-42. http://d.wanfangdata.com.cn/Periodical/hfgy200001011
    [11]
    张为鹏, 赵省向, 张亦安.杂质对硝酸铵溶液热分解特性的影响[J].化肥工业, 2000, 28(4): 12-14; 45. http://d.wanfangdata.com.cn/Periodical/hfgy200104004

    Zhang Wei-peng, Zhao Sheng-xiang, Zhang Yi-an. Effect of impurities on thermal decomposition properties of ammonium nitrate solution[J]. Chemical Fertilizer Industry, 2000, 28(4): 12-14; 45. http://d.wanfangdata.com.cn/Periodical/hfgy200104004
    [12]
    陈网桦, 陈利平, 吴燕, 等.硝酸及氯离子对高温硝酸铵水溶液热危险性的影响研究[J].中国安全科学学报, 2007, 17(5): 101-105. http://d.wanfangdata.com.cn/Periodical/zgaqkxxb200705018

    Chen Wang-hua, Chen Li-ping, Wu Yan, et al. Influence of nitrate acid and chlorine ion on the decomposition of ammonium nitrate in aqueous solution with high temperature[J]. China Safety Science Journal, 2007, 17(5): 101-105. http://d.wanfangdata.com.cn/Periodical/zgaqkxxb200705018
    [13]
    唐双凌, 吕春绪, 周新利, 等.改性硝酸铵爆炸安全性研究----Ⅱ.无机化学肥料对硝酸铵爆轰安全性的影响[J].应用化学, 2004, 21(4): 400-404. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=yyhx200404017

    Tang Shuang-ling, Lü Chun-xu, Zhou Xin-li, et al. Studies on the detonation safety of modified ammonium nitrate-Ⅱ. The influence of inorganic chemical fertilizer[J]. Chinese Journal of Applied Chemistry, 2004, 21(4): 400-404. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=yyhx200404017
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