Volume 40 Issue 5
May  2020
Turn off MathJax
Article Contents
ZHOU Jie, ZHI Xiaoqi, WANG Shuai, HAO Chunjie. Rheological properties of Composition B in slow cook-off process[J]. Explosion And Shock Waves, 2020, 40(5): 052301. doi: 10.11883/bzycj-2019-0321
Citation: ZHOU Jie, ZHI Xiaoqi, WANG Shuai, HAO Chunjie. Rheological properties of Composition B in slow cook-off process[J]. Explosion And Shock Waves, 2020, 40(5): 052301. doi: 10.11883/bzycj-2019-0321

Rheological properties of Composition B in slow cook-off process

doi: 10.11883/bzycj-2019-0321
  • Received Date: 2019-08-22
  • Rev Recd Date: 2019-10-10
  • Publish Date: 2020-05-01
  • In order to investigate the changes of the internal physical fields of melt-castable explosives in cook-off, Composition B was chosen as the object. A complete viscosity model of Composition B based on the Bingham flow model was first established, and then applied in the numerical simulations of slow cook-off. In this way, the temperature curves of three inner measuring pointsthat located in the upper, middle and lower respectively were obtained and further testified with cook-off experimental measurements. Moreover, the variation of the inner temperature field in the whole process was observed as well. The results showed that when the heating rate was 1 ℃/min, the viscosity flow of Composition B appeared soon after the phase change, and the inner temperature field changed with that. The self-heating and ignition occurred in the upside area of the shell. But when the heating rate was 0.055 ℃/min, the inner temperature field was still like a solid phase after the phase change was completely done for a long time, and the viscosity flow appeared after the self-heating started, the inner temperature field gradually began to change like a liquid phase just at that time. The ignition area was in the upside of the shell too, but the self-heating area was in the middle of the shell. The contradictory points of view in previous studies can be preliminarily explained by this model.
  • loading
  • [1]
    智小琦. 弹箭炸药装药技术 [M]. 北京: 兵器工业出版社, 2012: 7−8.

    ZHI X Q. Charge technology of explosive on projectile and rocket [M]. Beijing: Ordnance Industry Press, 2012: 7−8.
    [2]
    HOBBS M L, KANESHIGE M J, ERIKSON W W. Predicting large-scale effects during cookoff of PBXs and melt-castable explosives [C] // Proceedings of the 26th International Colloquium on the Dynamics of Explosions and Reactive Systems. Boston: MA: OSTI, 2017: 152−158.
    [3]
    MAIENSCHEIN J L, McCLELLAND M A, WARDELL J F, et al. ALE3D model predictions and experimental analysis of the cookoff response of Comp B [C] // Proceedings of Joint Army Navy NASA Air Force (JANNAF) Meeting. Colorado Springs, CO, USA: LLNL, 2003: 51−64.
    [4]
    GLASCOE E A, DEHAVEN M R, MCCLELLAND M, et al. Mechanisms of Comp-B thermal explosions [C] // Proceedings of the 15th International Detonation Symposium. San Francisco: LLNL, 2014: 376−385.
    [5]
    NICHOLS A L, SCHOFIELD S. Modeling the response of fluid/melt explosives to slow cook-off [C] // Proceedings of the 15th International Detonation Symposium. San Francisco: LLNL, 2014: 1128−1136.
    [6]
    FEDOROFF B T, SHEFFIELD O E, KAYE S M. Encyclopedia of explosives and related items [M]. Dover, NJ: Picatinny Arsenal, 1962.
    [7]
    HOBBS M L, KANESHIGE M J, ANDERSON M U. Cookoff of a melt-castable explosive (COMP-B) [C] // Proceedings of the 27th Propulsion Systems Hazards Joint Subcommittee Meeting. Monterrey: SNL-NM, 2012: 1020−1034.
    [8]
    SANHYE W, DUBOIS C, LAROCHE I, et al. Numerical modeling of the cooling cycle and associated thermal stresses in a melt explosive charge [J]. AIChE Journal, 2016, 62(10): 3797–3811. DOI: 10.1002/aic.15288.
    [9]
    NUNEZ M P, ZERKLE D K, ZUCKER J M. The rheology of molten Composition B [R]. NM: Los Alamos, 2012.
    [10]
    ZERKLE D K, NUNEZ M P, ZUCKER J M. Molten composition B viscosity at elevated temperature [J]. Journal of Energetic Materials, 2016, 34(4): 368–383. DOI: 10.1080/07370652.2015.1102179.
    [11]
    DAVIS S M, ZERKLE D K, SMILOWITZ L B, et al. Integrated rheology model: explosive composition B-3 [J]. Journal of Energetic Materials, 2018, 36(4): 398–411. DOI: 10.1080/07370652.2018.1451573.
    [12]
    DAVIS S M, ZERKLE D K. Short communication: estimation of yield stress/viscosity of molten Octol [J]. AIP Advances, 2018, 8(5): 055202.
    [13]
    MACOSKO C W. Rheology principles, measurements and applications [M]. New York: VCH Publishers, 1994: 92−98.
    [14]
    MORRISON F A. Understanding rheology [M]. New York: Oxford University Press, 2001: 232.
    [15]
    QUEMADA D. Rheology of concentrated disperse systems and minimum energy dissipation principle: I. viscosity-concentration relationship [J]. Rheologica Acta, 1977, 16(1): 82–94. DOI: 10.1007/BF01516932.
    [16]
    ZHOU J Z Q, UHLHERR P H, LUO F T. Yield stress and maximum packing fraction of concentrated suspensions [J]. Rheologica Acta, 1995, 34(6): 544–561. DOI: 10.1007/BF00712315.
    [17]
    Fluent Inc. FLUENT user’s guide [M]. US: Fluent Inc, 2006.
    [18]
    MCCLELLAND M A, GLASCOE E A, NICHOLS A L, et al. ALE3D simulation of incompressible flow, heat transfer, and chemical decomposition of Comp B in slow cookoff experiments [C] // Proceedings of International Detonation Symposium. San Francisco: LLNL, 2014: 517−528.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Figures(14)  / Tables(6)

    Article Metrics

    Article views (3741) PDF downloads(64) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return