Volume 41 Issue 9
Sep.  2021
Turn off MathJax
Article Contents
XIE Jibiao, ZHANG Jiaqi, DING Ce, WANG Xiaoli. Coupling relationship between flame velocity and overpressure of butane explosion inhibited by synergistic effect of nanohydrophobic SiO2[J]. Explosion And Shock Waves, 2021, 41(9): 095402. doi: 10.11883/bzycj-2021-0016
Citation: XIE Jibiao, ZHANG Jiaqi, DING Ce, WANG Xiaoli. Coupling relationship between flame velocity and overpressure of butane explosion inhibited by synergistic effect of nanohydrophobic SiO2[J]. Explosion And Shock Waves, 2021, 41(9): 095402. doi: 10.11883/bzycj-2021-0016

Coupling relationship between flame velocity and overpressure of butane explosion inhibited by synergistic effect of nanohydrophobic SiO2

doi: 10.11883/bzycj-2021-0016
  • Received Date: 2021-01-13
  • Rev Recd Date: 2021-03-22
  • Available Online: 2021-08-26
  • Publish Date: 2021-09-14
  • In order to explore the coupling of flame propagation velocity and pressure in butane gas explosion under the action of hydrophobic SiO2 powder as flame retardant and flow-enhancing additive, experiments were carried out on a self-designed and constructed $\varnothing $100 mm×1 000 mm explosion test platform based on LabVIEW system. The agglomeration of powder and the mechanism of powder explosion suppression were analyzed through energy dispersive spectrometer (EDS) and thermogravimetric (TG). The effects of different proportion and concentration of hydrophobic nano SiO2 powder on improving the flowability of CaCO3 powder and synergistically inhibiting butane explosion,and the coupling relationship between flame propagation velocity and pressure change were studied. The results show that the addition of hydrophobic SiO2 can reduce the angle of repose of the mixed powder and enhance the flowability. The residual amount of the powder decreases after spraying the powder, which proves that the diffusion effect and storability of the powder have been improved. Meanwhile, changing the proportion and concentration of the mixed powder has a significant effect on the combustion reaction. Within a certain concentration range, the powder is combined with the free radicals in the combustion area through larger specific surface area and pyrolysis, which significantly reduces the flame propagation velocity and explosion overpressure. However, excessive powder concentration promotes the explosion at the early stage, and the inhibition effect of the two powders on explosion is better than that of the single powder. Under the inhibition of the mixed powder, the flame velocity almost drops to the minimum when the explosion pressure reaches the maximum, and the pressure waveform changes from continuous rise to a single-peak curve. In addition, when the concentration is 106 g/m3 and the two powders are mixed in a mass ratio of 1∶1, the explosion suppression effect on 4.20% volume fraction butane-air mixture is the best, and the attenuation rates of average flame propagation velocity and maximum explosion overpressure are 85.5% and 59.6%, respectively, which effectively suppress the flame propagation velocity and explosion pressure.
  • loading
  • [1]
    李重情, 穆朝民, 许登科, 等. 空腔长度对瓦斯爆炸冲击波传播影响研究 [J]. 采矿与安全工程学报, 2018, 35(6): 1293–1300. DOI: 10.13545/j.cnki.jmse.2018.06.028.

    LI Z Q, MU C M, XU D K, et al. Influence of cavity length on shock wave propagation of gas explosion [J]. Journal of Mining & Safety Engineering, 2018, 35(6): 1293–1300. DOI: 10.13545/j.cnki.jmse.2018.06.028.
    [2]
    CHENG J W. Explosions in underground coal mines: risk assessment and control [M]. Cham: Springer, 2018: 2-20.
    [3]
    DUPLESSIS J J L. Active explosion barrier performance against methane and coal dust explosions [J]. International Journal of Coal Science & Technology, 2015, 2(4): 261–268. DOI: 10.1007/s40789-015-0097-7.
    [4]
    李润之. 瓦斯煤尘共存条件下的煤尘云爆炸下限 [J]. 爆炸与冲击, 2018, 38(4): 913–917. DOI: 10.11883/bzycj-2016-0331.

    LI R Z. Minimum explosive concentration of coal dust cloud in the coexistence of gas and coal dust [J]. Explosion and Shock Waves, 2018, 38(4): 913–917. DOI: 10.11883/bzycj-2016-0331.
    [5]
    ZHANG J J, XU K L, YOU G, et al. Causation analysis of risk coupling of gas explosion accident in Chinese underground coal mines [J]. Risk Analysis, 2019, 39(7): 1634–1646. DOI: 10.1111/risa.13311.
    [6]
    LU C, ZHANG Y, ZHU H, et al. Spurting NH4H2PO4 powder to prevent the propagation of gas explosion along the duct [J]. Combustion Science and Technology, 2020: 1–19. DOI: 10.1080/00102202.2020.1748607.
    [7]
    HUANG D M, WANG X Q, YANG J. Influence of particle size and heating rate on decomposition of BC Dry chemical fire extinguishing powders [J]. Particulate Science and Technology, 2015, 33(5): 488–493. DOI: 10.1080/02726351.2015.1013591.
    [8]
    LIU Q M, HU Y L, BAI C H, et al. Methane/coal dust/air explosions and their suppression by solid particle suppressing agents in a large-scale experimental tube [J]. Journal of Loss Prevention in the Process Industries, 2013, 26(2): 310–316. DOI: 10.1016/j.jlp.2011.05.004.
    [9]
    CHEN X F, ZHANG Y, ZHANG Q M, et al. Experimental investigation on micro-dynamic behavior of gas explosion suppression with SiO2 fine powders [J]. Theoretical and Applied Mechanics Letters, 2011, 1(3): 032004. DOI: 10.1063/2.1103204.
    [10]
    LUO Z M, WANG T, TIAN Z H, et al. Experimental study on the suppression of gas explosion using thegas–solid suppressant of CO2/ABC powder [J]. Journal of Loss Prevention in the Process Industries, 2014, 30: 17–23. DOI: 10.1016/j.jlp.2014.04.006.
    [11]
    GAO R J, YAO Y, WU H, et al. Effect of amphoteric dispersant on the dispersion properties of nano-SiO2 particles [J]. Journal of Applied Polymer Science, 2017, 134(29): 45075. DOI: 10.1002/app.45075.
    [12]
    MENG T, YU H M, LIAN S S, et al. Effect of nano‐SiO2 on properties and microstructure of polymer modified cementitious materials at different temperatures [J]. Structural Concrete, 2020, 21(2): 794–803. DOI: 10.1002/suco.201900170.
    [13]
    ZHU J, XU C B, HUANG Q, et al. Improving fluidizability of cohesive particles by surface coating with flow conditioners [C]//Proceedings of the Fifth World Congress on Particle Technology. Florida: AiChE, 2006: 1−9.
    [14]
    ANTHONY J L, MARONE C. Influence of particle characteristics on granular friction [J]. Journal of Geophysical Research: Solid Earth, 2005, 110(B8): B08409. DOI: 10.1029/2004JB003399.
    [15]
    SAENKO E V, HUO Y, SHAMSUTDINOV A S, et al. Mesoporous hydrophobic silica nanoparticles as flow-enhancing additives for fire and explosion suppression formulations [J]. ACS Applied Nano Materials, 2020, 3(3): 2221–2233. DOI: 10.1021/acsanm.9b02309.
    [16]
    王维, 刘玉硕, 房冉冉, 等. 疏水性可调型纳米二氧化硅的制备 [J]. 中国粉体技术, 2018, 24(4): 44–48. DOI: 10.13732/j.issn.1008-5548.2018.04.009.

    WANG W, LIU Y S, FANG R R, et al. Preparation of hydrophobic adjustable nano-silica [J]. China Powder Science and Technology, 2018, 24(4): 44–48. DOI: 10.13732/j.issn.1008-5548.2018.04.009.
    [17]
    王浩杰, 张嘉琪, 王丽, 等. 基于LabVIEW的多场景环境监测系统优化设计 [J]. 仪表技术与传感器, 2019(10): 66–70. DOI: 10.3969/j.issn.1002-1841.2019.10.016.

    WANG H J, ZHANG J Q, WANG L, et al. Optimization design of multi-scene environment monitoring system based on LabVIEW [J]. Instrument Technique and Sensor, 2019(10): 66–70. DOI: 10.3969/j.issn.1002-1841.2019.10.016.
    [18]
    FROLOVA S M, GEL'FAND B E. Shockwave attenuation in gas suspensions [J]. Combustion, Explosion and Shock Waves, 1991, 27(1): 124–129. DOI: 10.1007/bf00785372.
    [19]
    SOMMERFELD M. The unsteadiness of shock waves propagating through gas-particle mixtures [J]. Experiments in Fluids, 1985, 3(4): 197–206. DOI: 10.1007/BF00265101.
    [20]
    OLIM M, BEN-DOR G, MOND M, et al. A general attenuation law of moderate planar shock waves propagating into dusty gases with relatively high loading ratios of solid particles [J]. Fluid Dynamics Research, 1990, 6(3): 185–199. DOI: 10.1016/0169-5983(90)90061-3.
    [21]
    高正江, 张国庆, 李周, 等. 粉末粒度和氧含量对HIP态FGH96合金组织的影响 [J]. 稀有金属, 2012, 36(4): 665–670. DOI: 10.3969/j.issn.0258-7076.2012.04.026.

    GAO Z J, ZHANG G Q, LI Z, et al. Effect of size distribution and oxygen content of powder on microstructure of HIPed superalloy FGH96 [J]. Chinese Journal of Rare Metals, 2012, 36(4): 665–670. DOI: 10.3969/j.issn.0258-7076.2012.04.026.
    [22]
    程方明, 邓军, 罗振敏, 等. 硅藻土粉体抑制瓦斯爆炸的实验研究 [J]. 采矿与安全工程学报, 2010, 27(4): 604–607. DOI: 10.3969/j.issn.1673-3363.2010.04.031.

    CHENG F M, DENG J, LUO Z M, et al. Experimental study on inhibiting gas explosion using diatomite powder [J]. Journal of Mining & Safety Engineering, 2010, 27(4): 604–607. DOI: 10.3969/j.issn.1673-3363.2010.04.031.
    [23]
    丁浩青, 温小萍, 邓浩鑫, 等. 障碍物条件下纳米SiO2粉体抑制瓦斯爆炸特性 [J]. 安全与环境学报, 2017, 17(3): 958–962. DOI: 10.13637/j.issn.1009-6094.2017.03.028.

    DING H Q, WEN X P, DENG H X, et al. Suppression function of SiO2 nanoparticles against the gas explosion in the presence of obstacles [J]. Journal of Safety and Environment, 2017, 17(3): 958–962. DOI: 10.13637/j.issn.1009-6094.2017.03.028.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Figures(9)  / Tables(1)

    Article Metrics

    Article views (379) PDF downloads(31) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return