Volume 42 Issue 11
Nov.  2022
Turn off MathJax
Article Contents
BAO Yangfan, WANG Han, LI Zhigang. Effects of laser irradiation on the structure and mechanical-electrical properties of graphene oxide thin films[J]. Explosion And Shock Waves, 2022, 42(11): 115301. doi: 10.11883/bzycj-2021-0431
Citation: BAO Yangfan, WANG Han, LI Zhigang. Effects of laser irradiation on the structure and mechanical-electrical properties of graphene oxide thin films[J]. Explosion And Shock Waves, 2022, 42(11): 115301. doi: 10.11883/bzycj-2021-0431

Effects of laser irradiation on the structure and mechanical-electrical properties of graphene oxide thin films

doi: 10.11883/bzycj-2021-0431
  • Received Date: 2021-10-10
  • Rev Recd Date: 2022-01-25
  • Available Online: 2022-10-17
  • Publish Date: 2022-11-18
  • Graphene has high specific strength and stiffness, high current-carrier mobility, low resistivity, and even exceptive electromagnetic properties, which is expected as a next-generation micro-nano photoelectric material. However, most research and applications of graphene materials and photoelectric devices are still only in the laboratory stage. On the one hand, limited to current technologies, industrial mass-scale production of high-quality monolayer graphene films is impossible. On the other hand, the micro-scale patterned machining process may bring structural and performance damage to the material, making the stability and reliability of devices difficult to guarantee. In recent years, with the innovation and progress of laser processing technology, the micro-nano-scale patterned processing of graphene oxide (GO) thin films by laser has become a key technology for solving the development of integrated circuits and information communication equipment to precision and miniaturization. The existing achievements mainly focus on the process and method of laser processing graphene materials with different structures, the physical mechanism of interaction between ultrafast laser and monolayer graphene film, etc. The deformation and damage mechanism of graphene films at ultra-high strain rates are still unclear. In particular, the industrial application of micron-scale multilayer reduced graphene oxide (RGO) films has been much widely explored. However, few studies have been conducted on their mechano-thermal and complex physical processes associated with laser shock and the resulting interlayer damage due to the weak interlayer bonding force. To study the effect of ultrahigh strain rate load on the structure and properties of GO films, GO films were prepared by pumping a certain concentration of GO solution onto the membrane. The reduced GO films were obtained by laser ablation with different laser powers. The mechanism of the film’s structural change was revealed by the characterization of its surface morphology and chemical composition. Reasonable laser machining parameters were explored by measuring the hardness, elastic modulus, and conductivity of film before and after impact. The results show that the film can be reduced without ablative fracture under CO2 laser shock at 1.14 W power. Its electrical conductivity can reach 1.727×103 S/m, the elastic modulus is 49.97 GPa, and hardness is 5.71 GPa.
  • loading
  • [1]
    WONG S I, LIN H, SUNARSO J, et al. Optimization of ionic-liquid based electrolyte concentration for high-energy density graphene supercapacitors [J]. Applied Materials Today, 2020, 18: 100522. DOI: 10.1016/j.apmt.2019.100522.
    [2]
    LIN D, MOTLAG M, SAEI M, et al. Shock engineering the additive manufactured graphene-metal nanocomposite with high density nanotwins and dislocations for ultra-stable mechanical properties [J]. Acta Materialia, 2018, 150: 360–372. DOI: 10.1016/j.actamat.2018.03.013.
    [3]
    BATAKLIEV T, GEORGIEV V, IVANOV E, et al. Nanoindentation analysis of 3D printed poly (lactic acid)-based composites reinforced with graphene and multiwall carbon nanotubes [J]. Journal of Applied Polymer Science, 2019, 136(13): 47260. DOI: 10.1002/app.47260.
    [4]
    张倩, 唐利斌, 李汝劼, 等. 氧化石墨烯的制备还原及应用进展 [J]. 红外与毫米波学报, 2019, 38(1): 79–90. DOI: 10.11972/j.issn.1001-9014.2019.01.014.

    ZHANG Q, TANG L B, LI R J, et al. Graphene oxide: progress in preparation, reduction and application [J]. Journal of Infrared and Millimeter Waves, 2019, 38(1): 79–90. DOI: 10.11972/j.issn.1001-9014.2019.01.014.
    [5]
    GE L, HONG Q, LI H, et al. Direct-laser-writing of metal sulfide-graphene nanocomposite photoelectrode toward sensitive photoelectrochemical sensing [J]. Advanced Functional Materials, 2019, 29(38): 1904000. DOI: 10.1002/adfm.201904000.
    [6]
    严如玉. 石墨烯膜和氧化石墨烯膜的飞秒激光微纳加工 [D]. 北京: 北京理工大学, 2016. DOI: 10.26948/d.cnki.gbjlu.2016.000774.

    YAN R Y. Femtosecond laser processing of graphene films and graphene oxide films [D]. Beijing: Beijing Institute of Technology, 2016. DOI: 10.26948/d.cnki.gbjlu.2016.000774.
    [7]
    刘璇, 王鹏波, 李必奎, 等. 皮秒激光直写还原石墨烯氧化物薄膜的研究 [J]. 光电子·激光, 2017, 28(10): 1096–1100. DOI: 10.16136/j.joel.2017.10.0057.

    LIU X, WANG P B, LI B K, et al. Study on reduction of graphene oxide films using picosecond laser direct writing [J]. Journal of Optoelectronics Laser, 2017, 28(10): 1096–1100. DOI: 10.16136/j.joel.2017.10.0057.
    [8]
    GONÇALVES G, BORME J, BDKIN I, et al. Reductive nanometric patterning of graphene oxide paper using electron beam lithography [J]. Carbon, 2018, 129: 63–75. DOI: 10.1016/j.carbon.2017.11.067.
    [9]
    GUO L, SHAO R Q, ZHANG Y L, et al. Bandgap tailoring and synchronous microdevices patterning of graphene oxides [J]. The Journal of Physical Chemistry C, 2012, 116(5): 3594–3599. DOI: 10.1021/jp209843m.
    [10]
    CHEN H Y, HAN D D, TIAN Y, et al. Mask-free and programmable patterning of graphene by ultrafast laser direct writing [J]. Chemical Physics, 2014, 430: 13–17. DOI: 10.1016/j.chemphys.2013.12.005.
    [11]
    韩同伟, 贺鹏飞, 王健, 等. 单层石墨烯薄膜拉伸变形的分子动力学模拟 [J]. 新型炭材料, 2010, 25(4): 261–266.

    HAN T W, HE P F, WANG J, et al. Molecular dynamics simulation of a single graphene sheet under tension [J]. New Carbon Materials, 2010, 25(4): 261–266.
    [12]
    PEI C, UEDA T, ZHU J H. Investigation of the effectiveness of graphene/polyvinyl alcohol on the mechanical and electrical properties of cement composites [J]. Materials and Structures, 2020, 53(3): 66. DOI: 10.1617/s11527-020-01508-6.
    [13]
    WO F J, XU R J, SHAO Y X, et al. A multimodal system with synergistic effects of magneto-mechanical, photothermal, photodynamic and chemo therapies of cancer in graphene-quantum dot-coated hollow magnetic Nanospheres [J]. Theranostics, 2016, 6(4): 485–500. DOI: 10.7150/thno.13411.
    [14]
    DHONGADE S, KOINKAR P, FURUBE A, et al. Liquid exfoliation of graphene oxide nanoribbons using chemical assisted laser ablation [J]. International Journal of Modern Physics B, 2021, 35(14n16): 2140009. DOI: 10.1142/S0217979221400099.
    [15]
    YOGESH G K, SHUAIB E P, ROOPMANI P, et al. Synthesis, characterization and bioimaging application of laser-ablated graphene-oxide nanoparticles (nGOs) [J]. Diamond and Related Materials, 2020, 104: 107733. DOI: 10.1016/j.diamond.2020.107733.
    [16]
    EL-KADY M F, STRONG V, DUBIN S, et al. Laser scribing of high-performance and flexible graphene-based electrochemical capacitors [J]. Science, 2012, 335(6074): 1326–1330. DOI: 10.1126/science.1216744.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Figures(6)  / Tables(2)

    Article Metrics

    Article views (262) PDF downloads(29) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return