Volume 40 Issue 6
Jun.  2020
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LIU Erwei, XU Shengli. Influence of ignition criterion and dilution gas on ignition delay of ethylene[J]. Explosion And Shock Waves, 2020, 40(6): 062101. doi: 10.11883/bzycj-2019-0402
Citation: LIU Erwei, XU Shengli. Influence of ignition criterion and dilution gas on ignition delay of ethylene[J]. Explosion And Shock Waves, 2020, 40(6): 062101. doi: 10.11883/bzycj-2019-0402

Influence of ignition criterion and dilution gas on ignition delay of ethylene

doi: 10.11883/bzycj-2019-0402
  • Received Date: 2019-10-21
  • Rev Recd Date: 2019-12-12
  • Publish Date: 2020-06-01
  • Ignition delay of ethylene (C2H4) are measured under different temperatures in a rectangle shock tube to recognize the effects from diluent gases (nitrogen or argon) and criteria which is identified by pressure, bulk and radical chemiluminescences of OH and CH at specified wavelengths. Pressures were recorded by piezoelectric sensors (PCBs), and bulk chemiluminescence was detected by a photomultiplier (PMT) and an optical fiber. The chemiluminescences of OH and CH radicals were grated by spectrometer first, and then recorded by the PMT. The ignition delay is determined from the pressure and intensity histories of bulk and radical chemiluminescences at the points which share the same distances from the close end. Ignition delay database was built for mixture of C2H4/O2/N2 and C2H4/O2/Ar. Measurement and methodology are verified by the repeated experimental data under the same conditions. In the case of stoichimetric equivalence and pressure at 0.2 MPa, ignition delays were obtained and fitted with temperature as Arrhenius formula for mixtures of C2H4/O2/N2 and C2H4/O2/Ar at temperature ranging from 905 K to 1 489 K. Results show that the relative error of ignition delays is about 15%. Based on pressure, bulk and radical chemiluminescences, the relationships between the ignition delay and temperature remain the same although the ignition delay from single measurement is a bit different. Basically, the ignition delay of C2H4/O2/N2 is greater than that of C2H4/O2/Ar. The fitting relationship between ignition delay and temperature of C2H4/O2 /Ar in high temperature zone and low temperature zone is different, and the turning temperature is about 1 121 K.
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  • [1]
    KUO K K. Principles of combustion [M]. New York: John Wiley & Sons Inc., 1986.
    [2]
    HANSON R K, DAVIDSON D F. Recent advances in laser absorption and shock tube methods for studies of combustion chemistry [J]. Progress in Energy and Combustion Science, 2014, 44(5): 103–114.
    [3]
    BARARI G, PRYOR O, KOROGLU B, et al. High temperature shock tube experiments and kinetic modeling study of diisopropyl ketone ignition and pyrolysis [J]. Combustion and Flame, 2017, 177: 207–218. DOI: 10.1016/j.combustflame.2016.12.003.
    [4]
    REN W, DAVIDSON D F, HANSON R K. IR laser absorption diagnostic for C2H4 in shock tube kinetics studies [J]. International Journal of Chemical Kinetics, 2012, 44(6): 423. DOI: 10.1002/kin.20599.
    [5]
    ROOSE T R, HANSON R K, KRUGER C H. A shock tube study of the decomposition of NO in the presence of NH3 [C] // Symposium (International) on Combustion, 1981, 18(1): 853-862.
    [6]
    胡弘浩. 乙烯点火特性及其污染效应的激波管研究[D]. 重庆: 重庆大学, 2012.

    HU H H. A shock tube study of ignition delay characteristics of ethylene and contamination effect [D]. Chongqing: Chongqing University, 2012.
    [7]
    BAKER J A, SKINNER G B. Shock-tube studies on the ignition of ethylene-oxygen-argon mixtures [J]. Combustion and Flame, 1972, 19(3): 347–350. DOI: 10.1016/0010-2180(72)90004-1.
    [8]
    SUZUKI M, MORIWAKI T, OKAZAKI S, et al. Oxidation of ethylene in shock tube [J]. Astronautica Acta, 1973, 18(5): 359–365.
    [9]
    BROWN C J, THOMAS G O. Experimental studies of shock-induced ignition and transition to detonation in ethylene and propane mixtures [J]. Combustion and Flame, 1999, 117(4): 861–870. DOI: 10.1016/S0010-2180(98)00133-3.
    [10]
    CADMAN P, BAMBREY R J, BOX S K, et al. Ethylene combustion studied over a wide temperature range in high-temperature shock waves [J]. Combustion Science and Technology, 2002, 174(11-2): 111–127.
    [11]
    SAXENA S, KAHANDAWALA M S P, SIDHU S S. A shock tube study of ignition delay in the combustion of ethylene [J]. Combustion and Flame, 2011, 158(6): 1019–1031. DOI: 10.1016/j.combustflame.2010.10.011.
    [12]
    梁金虎. 煤油点火延时特性及其污染效应的激波管研究[D]. 重庆: 重庆大学, 2011.

    LIANG J H. Ignition delay characteristics study of kerosene and contaminated kerosene in shock tube [D]. Chongqing: Chongqing University, 2011.
    [13]
    DENG F Q, PAN Y S, SUM W C, et al. Comparative study of the effects of nitrous oxide and oxygen on ethylene ignition [J]. Energy and Fuels, 2017, 31(12): 14116–14128. DOI: 10.1021/acs.energyfuels.7b01425.
    [14]
    廖钦. 煤油及其裂解产物自点火现象的初步实验研究[D]. 合肥: 中国科学技术大学, 2009.

    LIAO Q. Experimental studies on auto-ignition phenomena of kerosene and cracked kerosene in a shock tube [D]. Hefei: University of Science and Technology of China, 2009.
    [15]
    PENYAZKOV O G, SEVROUK K L, TANGIRALA V, et al. High-pressure ethylene oxidation behind reflected shock waves [J]. Proceedings of the Combustion Institute, 2009, 32(2): 2421–2428. DOI: 10.1016/j.proci.2008.06.194.
    [16]
    SMITH G P, GOLDEN D M, FRENKLACH M, et al. An optimized detailed chemical reaction mechanism for methane combustion: PB-96-137054/XAB[R]. SRI International, 1995.
    [17]
    SARATHY S M, WESTBROOK C K, MEHL M, et al. Comprehensive chemical kinetic modeling of the oxidation of 2-methylalkanes from C7 to C20 [J]. Combustion and Flame, 2011, 158: 2338–2357. DOI: 10.1016/j.combustflame.2011.05.007.
    [18]
    JOSHI A, YOU X Q, BARCKHOLTZ T A, et al. Thermal decomposition of ethylene oxide: potential energy surface, master equation analysis, and detailed kinetic modeling [J]. Journal of Physical Chemistry A, 2005, 109(35): 8016–8027. DOI: 10.1021/jp0516442.
    [19]
    DAVIDSON D F, HANSON R K. Interpreting shock tube ignition data [J]. International Journal of Chemical Kinetics, 2004, 36(9): 510–523. DOI: 10.1002/kin.20024.
    [20]
    WURMEL J, SILKE E J, CURRAN H J, et al. The effect of diluent gases on ignition delay times in the shock tube and in the rapid compression machine [J]. Combustion and Flame, 2007, 151(1-2): 289–302. DOI: 10.1016/j.combustflame.2007.06.010.
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