Study on hydrogen-oxygen detonation process and the growth of carbon-iron nanomaterials in a detonation tube

ZHAO Tiejun; LIU Yi; WU Yongxiang; YAN Honghao; WU Linsong

doi:10.11883/bzycj-2023-0404

Volume 44 Issue 11

Nov. 2024

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ZHAO Tiejun, LIU Yi, WU Yongxiang, YAN Honghao, WU Linsong. Study on hydrogen-oxygen detonation process and the growth of carbon-iron nanomaterials in a detonation tube[J]. Explosion And Shock Waves, 2024, 44(11): 112101. doi: 10.11883/bzycj-2023-0404

Citation:

ZHAO Tiejun, LIU Yi, WU Yongxiang, YAN Honghao, WU Linsong. Study on hydrogen-oxygen detonation process and the growth of carbon-iron nanomaterials in a detonation tube[J]. Explosion And Shock Waves, 2024, 44(11): 112101. doi: 10.11883/bzycj-2023-0404

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Study on hydrogen-oxygen detonation process and the growth of carbon-iron nanomaterials in a detonation tube

doi: 10.11883/bzycj-2023-0404

1.
College of Civil Engineering and Architecture, Henan University, Kaifeng 475000, Henan, China
2.
Department of Engineering Mechanics, Dalian University of Technology, Dalian 116024, Liaoning, China
3.
School of Urban Architecture, Yangtze University, Jingzhou 434023, Hubei, China

Received Date: 2023-11-10
Rev Recd Date: 2023-12-04

Available Online: 2024-03-26

Publish Date: 2024-11-15

Abstract

Abstract

To study the explosion process of carbon-iron nanomaterials synthesized by gaseous detonation, the effects of different molar ratios of hydrogen to oxygen (2∶1, 3∶1, 4∶1) on the peak value time-history curve of detonation parameters (detonation velocity, detonation temperature, and detonation pressure) and the morphology of carbon-iron nanomaterials were studied by combination of hydrogen-oxygen experiments and numerical simulations. The explosion experiments used hydrogen and oxygen with a purity of 99.999% in a closed detonation tube. The precursor was ferrocene with a purity of 99%. A high-speed camera was used to observe in the middle of the tube. After the experiments, the samples were collected and characterized by transmission electron microscopy. The numerical simulation used ICEM software for modeling and meshing and then used Fluent software to verify the rationality of the mesh size, and then performed simulation calculations after confirming the optimal mesh size. The results indicate that hydrogen-oxygen explosion inside a detonation tube involves two processes: the propagation of detonation waves and the attenuation of combustion waves, and the hydrogen-oxygen molar ratio has a significant impact on the peak time history curves of detonation velocity, detonation temperature, and detonation pressure. With the increase of the molar ratio of hydrogen to oxygen, the detonation velocity, detonation temperature, detonation pressure, and attenuation rate of the detonation wave all decrease. The molar ratio of hydrogen to oxygen affects the morphology growth of carbon-iron nanomaterials by influencing the propagation and attenuation of detonation waves. At zero oxygen balance, the sample consists of carbon-coated iron nanoparticles. As the hydrogen-oxygen molar ratio increases, the number of carbon nanotubes in the sample gradually increases. Adjusting the molar ratio of hydrogen to oxygen can achieve control over the propagation and attenuation process of detonation waves, and also achieve the goal of controlling the preparation of carbon iron nanomaterials with specific morphologies through gaseous detonation.
- detonation synthesis,
- molar ratio of hydrogen to oxygen,
- growth mechanism,
- carbon-iron nanomaterial

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References

[1]	WANG X S, VASILEFF A, JIAO Y, et al. Electronic and structural engineering of carbon-based metal-free electrocatalysts for water splitting [J]. Advanced Materials, 2019, 31(13): 1803625. DOI: 10.1002/adma.201803625.
[2]	YANG Z F, TIAN J R, YIN Z F, et al. Carbon nanotube- and graphene-based nanomaterials and applications in high-voltage supercapacitor: a review [J]. Carbon, 2019, 141: 467–480. DOI: 10.1016/j.carbon.2018.10.010.
[3]	LU F, ASTRUC D. Nanocatalysts and other nanomaterials for water remediation from organic pollutants [J]. Coordination Chemistry Reviews, 2020, 408: 213180. DOI: 10.1016/j.ccr.2020.213180.
[4]	CHARINPANITKUL T, TANTHAPANICHAKOON W, SANO N. Carbon nanostructures synthesized by arc discharge between carbon and iron electrodes in liquid nitrogen [J]. Current Applied Physics, 2009, 9(3): 629–632. DOI: 10.1016/j.cap.2008.05.018.
[5]	WANG X, XU B, LIU X, et al. Synthesis of Fe-included onion-like fullerenes by chemical vapor deposition [J]. Diamond and Related Materials, 2006, 15(1): 147–150. DOI: 10.1016/j.diamond.2005.09.005.
[6]	徐斌, 楼白杨, 曹小海, 等. 纳米铜修饰多壁碳纳米管/石蜡相变驱动复合材料的制备及热性能 [J]. 复合材料学报, 2015, 32(2): 427–434. DOI: 10.13801/j.cnki.fhclxb.20140723.001. XU B, LOU B Y, CAO X H, et al. Preparation and thermal properties of copper modified multi-walled carbon nanotubes/paraffin phase transition-driven composites [J]. Journal of Composite Materials, 2015, 32(2): 427–434. DOI: 10.13801/j.cnki.fhclxb.20140723.001.
[7]	张宏, 赵俊峰, 张锡兰, 等. ZnO/CNTs复合材料吸附脱除H₂S的性能研究 [J]. 化学研究, 2017, 28(5): 612–616. DOI: 10.14002/j.hxya.2017.05.014. ZHANG H, ZHAO J F, ZHANG X L, et al. Study on the adsorption and removal of H₂S by ZnO/CNTs composites [J]. Chinese Journal of Chemical Research, 2017, 28(5): 612–616. DOI: 10.14002/j.hxya.2017.05.014.
[8]	NEPAL A, SINGH G P, FLANDERS B N, et al. One-step synthesis of graphene via catalyst-free gas-phase hydrocarbon detonation [J]. Nanotechnology, 2013, 24(24): 245602. DOI: 10.1088/0957-4484/24/24/245602.
[9]	SHTERTSER A A, RYBIN D K, YU V Y, et al. Characterization of nanoscale detonation carbon produced in a pulse gas-detonation device [J]. Diamond and Related Materials, 2020, 101: 107553. DOI: 10.1016/j.diamond.2019.107553.
[10]	XIANG J X, LUO N, YAN H H, et al. Preparation and formation mechanism of spherical Cu nanoparticles by gaseous detonation [J]. Rare Metal Materials and Engineering, 2019, 48(10): 3113–3117.
[11]	ZHAO T J, WANG X H, LI X J, et al. Gaseous detonation synthesis of Co@C nanoparticles/CNTs materials [J]. Materials Letters, 2019, 236: 179–182. DOI: 10.1016/j.matlet.2018.10.105.
[12]	ZHAO T J, LI X J, JOHN L, et al. The effects of hydrogen proportion on the synthesis of carbon nanomaterials with gaseous detonation (deflagration) method [J]. Materials Research Express, 2018, 5(2):025024 DOI: 10.1088/2053-1591/aaadd6.
[13]	ZHAO T J, LI X J, WANG Y, et al. Growth mechanism and wave-absorption properties of multiwalled carbon nanotubes fabricated using a gaseous detonation method [J]. Materials Research Bulletin, 2018, 102: 153–159. DOI: 10.1016/j.materresbull.2018.02.033.
[14]	HE C, YAN H H, LI X J, et al. Ultrafast preparation of polymer carbon dots with solid-state fluorescence for white light-emitting diodes [J]. Materials Research Express, 2019, 6(6): 065609. DOI: 10.1088/2053-1591/ab0c42.
[15]	SHTERTSER A A, ULIANITSKY V Y, BATRAEV I S, et al. Production of nanoscale detonation carbon using a pulse gas-detonation device [J]. Technical Physics Letters, 2018, 44: 395–397. DOI: 10.1134/S1063785018050139.
[16]	闫鸿浩, 赵铁军, 孙贵磊, 等. 气相爆轰合成碳包铁的影响因素 [J]. 无机材料学报, 2016, 31(5): 542–546. DOI: 10.15541/jim20150544. YAN H H, ZHAO T J, SUN G L, et al. Influencing factors of carbon-clad iron synthesis by gas-phase detonation [J]. Journal of Inorganic Materials, 2016, 31(5): 542–546. DOI: 10.15541/jim20150544.
[17]	YAN H H, ZHANG X F, LI X J, et al. The influence of ar on the synthesis of carbon-coated copper nanoparticles in gaseous detonation [J]. Current Nanoscience, 2018, 14(5): 360–365. DOI: 10.2174/1573413714666180502130314.
[18]	杨瑞, 李晓杰, 闫鸿浩, 等. 初始温度及碳源对碳纳米管气相爆轰法合成的影响 [J]. 强激光与粒子束, 2017, 29(2): 56–60. DOI: 10.11884/HPLPB201729.160402. YANG R, LI X J, YAN H H, et al. Effects of initial temperature and carbon source on the synthesis of carbon nanotubes by vapor phase detonation [J]. High Power Laser and Particle Beams, 2017, 29(2): 56–60. DOI: 10.11884/HPLPB201729.160402.
[19]	FRY D, CHAKRABARTI A, KIM W, et al. Structural crossover in dense irreversibly aggregating particulate systems [J]. Physical Review E, 2004, 69(6): 061401. DOI: 10.1103/PhysRevE.69.061401.
[20]	DHAUBHADEL R, PIERCE F, CHAKRABARTI A, et al. Hybrid superaggregate morphology as a result of aggregation in a cluster-dense aerosol [J]. Physical Review E, 2006, 73(1): 011404. DOI: 10.1103/PhysRevE.73.011404.
[21]	KIM K, SORENSEN C M, CHAKRABARTI A. Universal occurrence of soot superaggregates with a fractal dimension of 2.6 in heavily sooting laminar diffusion flames [J]. Langmuir, 2004, 20(10): 3969–3973. DOI: 10.1021/la036085%2B.
[22]	李晓杰, 杨瑞, 闫鸿浩. 氧气浓度对气相爆轰合成纳米碳球的影响 [J]. 高压物理学报, 2017, 31(1): 15–20. DOI: 10.11858/gywlxb.2017.01.003. LI X J, YANG R, YAN H H. Effect of oxygen concentration on synthesis of carbon nanospheres by gas-phase detonation [J]. Chinese Journal of High Pressure Physics, 2017, 31(1): 15–20. DOI: 10.11858/gywlxb.2017.01.003.
[23]	LUO N, XIANG J X, SHEN T, et al. One-step gas-liquid detonation synthesis of carbon nano-onions and their tribological performance as lubricant additives [J]. Diamond and Related Materials, 2019, 97: 107448. DOI: 10.1016/j.diamond.2019.107448.
[24]	HE C, YAN H H, LI X J, et al. One-step rapid fabrication of high-purity onion-like carbons as efficient lubrication additives [J]. Journal of Materials Science, 2021, 56(2): 1286–1297. DOI: 10.1007/s10853-020-05311-0.
[25]	XIANG J X, LUO N, SHEN T, et al. Rapid synthesis of carbon/graphite encapsulated iron-based composite nanoparticles by a gaseous-liquid detonation [J]. Diamond and Related Materials, 2018, 90: 1–6. DOI: 10.1016/j.diamond.2018.09.017.
[26]	ZHAO T J, LI X J, YAN H H. Metal catalyzed preparation of carbon nanomaterials by hydrogen-oxygen detonation method [J]. Combustion and Flame, 2018, 196: 108–115. DOI: 10.1016/j.combustflame.2018.06.011.
[27]	赵铁军, 王自法, 闫鸿浩, 等. 气相爆轰反应中纳米TiO₂颗粒的动态收集及微观生长机制 [J]. 高压物理学报, 2021, 35(5): 053201. DOI: 10.11858/gywlxb.2021.07.046. ZHAO T J, WANG Z F, YAN H H, et al. Dynamic collection and microscopic growth mechanism of nano TiO₂ articles in gas-phase detonation reaction [J]. Chinese Journal of High Pressure Physics, 2021, 35(5): 053201. DOI: 10.11858/gywlxb.2021.07.046.
[28]	ZHAO T J, WU L S, WANG Z F, et al. Insight on the growth mechanism of TiO₂ nanoparticles via gaseous detonation intercepting collection [J]. Ceramics International, 2023, 49(6): 9857–9861. DOI: 10.1016/j.ceramint.2022.11.160.
[29]	YAN H H, ZHAO T J, LI X J, et al. Hydrogen and air detonation (deflagration) synthesis of carbon-encapsulated iron nanoparticles [J]. Combustion Explosion and Shock Waves, 2015, 51(4): 495–501. DOI: 10.1134/S0010508215040152.
[30]	YAN H H, HUN C H, LI X J, et al. Synthesis of carbon-encapsulated iron nanoparticles by gaseous detonation of hydrogen and oxygen at different temperatures within detonation tube [J]. Rare Metal Materials and Engineering, 2015, 44(9): 2152–2155. DOI: 10.1016/S1875-5372(16)30015-7.
[31]	闫鸿浩, 赵铁军, 李晓杰, 等. 碳包覆铁纳米颗粒的气相爆轰合成 [J]. 高压物理学报, 2016, 30(3): 207–212. DOI: 10.11858/gywlxb.2016.03.005. YAN H H, ZHAO T J, LI X J, et al. Vapor phase detonation synthesis of carbon-coated iron nanoparticles [J]. Chinese Journal of High Pressure Physics, 2016, 30(3): 207–212. DOI: 10.11858/gywlxb.2016.03.005.
[32]	潘训岑, 李雪琪, 李晓杰, 等. 气相爆轰法合成超细碳包铁纳米颗粒 [J]. 稀有金属材料与工程, 2019, 48(3): 981–986. PAN X C, LI X Q, LI X J, et al. Synthesis of ultrafine carbon-clad iron-clad nanoparticles by gas phase detonation method [J]. Rare Metal Materials and Engineering, 2019, 48(3): 981–986.