Volume 40 Issue 8
Aug.  2020
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JIA Hailin, ZHAI Rupeng, LI Dihui, XIANG Haijun, YANG Yongqin. Differences of premixed methane-air explosion in pipelines suppressed by three ultrafine water mists containing different salts[J]. Explosion And Shock Waves, 2020, 40(8): 082201. doi: 10.11883/bzycj-2019-0456
Citation: JIA Hailin, ZHAI Rupeng, LI Dihui, XIANG Haijun, YANG Yongqin. Differences of premixed methane-air explosion in pipelines suppressed by three ultrafine water mists containing different salts[J]. Explosion And Shock Waves, 2020, 40(8): 082201. doi: 10.11883/bzycj-2019-0456

Differences of premixed methane-air explosion in pipelines suppressed by three ultrafine water mists containing different salts

doi: 10.11883/bzycj-2019-0456
  • Received Date: 2019-12-13
  • Rev Recd Date: 2020-05-26
  • Publish Date: 2020-08-01
  • In order to solve the safety problem caused by flammable gas explosion in pipeline transportation, an experimental system for premixed gas explosion and explosion suppression in multiple pipelines was self-built. And then a series of premixed methane-air explosion and explosion suppression experiments were carried out under the ultrafine water mists without or with three kinds of salts in the different working conditions including the different salt mass fractions and the different mist fluxes. In the experiments, the methane volume fraction in the premixed methane-air mixture was 9.5%, and three salts used as additives were NaCl, NaHCO3 and MgCl2. According to the theories of fire science and explosion science, the different changes in the explosion characteristics were explored involving the oscillation curves and the maximum peak values of explosion overpressure, the front positions and the average propagation velocities of the explosion flame, the evolution images of the flame structure in pipe B. The results show that with the increases of salt mass fractions and ultrafine water mist fluxes with salts (NaCl, NaHCO3 and MgCl2), the maximum peaks of explosion overpressure decreased by different amplitudes compared with those under the action of pure water mist, the oscillation curves of explosion overpressure increased slowly, and the average propagation velocities of explosion flame decreased significantly. The explosion flame fronts receded different times in the pipe B. And the times when the explosion flames reached the terminal end of the pipe B delayed obviously compared with those with or without the pure ultrafine water mist. Comparisons display that the ultrafine water mist containing NaCl is superior to the ones containing MgCl2 and NaHCO3, respectively, in weakening the explosion overpressure, delaying the advance of the flame front position, decreasing the average flame propagation velocity, and reducing the receding times of the explosion flame front. The primary reason is that the ability of the anion Clto destroy OH· and H· radicals in chain explosion reactions is stronger than that of the anion ${\rm{HCO}}_3^- $ and the ability of the cation Na+ to destroy OH· and H· radicals in explosion reactions is stronger than that of the cation Mg2+.
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  • [1]
    毛宗强. 氢能: 我国未来的清洁能源 [J]. 化工学报, 2004, 55(S1): 296–302.

    MAO Z Q. Hydrogen: a future clean energy carrier in China [J]. Journal of Chemical Industry and Engineering, 2004, 55(S1): 296–302.
    [2]
    RAZUS D, MOVILEANU C, BRINZEA V, et al. Explosion pressures of hydrocarbon-air mixtures in closed vessels [J]. Journal of Hazardous Materials, 2006, 135(1−3): 58–65. DOI: 10.1016/j.jhazmat.2005.10.061.
    [3]
    KURDYUMOV V N, MATALON M. Flame acceleration in long narrow open channels [J]. Proceedings of the Combustion Institute, 2013, 34(1): 865–872. DOI: 10.1016/j.proci.2012.07.045.
    [4]
    WANG C, HUANG F L, ADDAI E K, et al. Effect of concentration and obstacles on flame velocity and overpressure of methane-air mixture [J]. Journal of Loss Prevention in the Process Industries, 2016, 43: 302–310. DOI: 10.1016/j.jlp.2016.05.021.
    [5]
    罗振敏, 王涛, 程方明, 等. 小尺寸管道内二氧化碳抑制甲烷爆炸效果的实验及数值模拟 [J]. 爆炸与冲击, 2015, 35(3): 393–400. DOI: 10.11883/1001-1455-(2015)03-0393-08.

    LUO Z M, WANG T, CHENG F M, et al. Experimental and numerical studies on the suppression of methane explosion using CO2 in a mini vessel [J]. Explosion and Shock Waves, 2015, 35(3): 393–400. DOI: 10.11883/1001-1455-(2015)03-0393-08.
    [6]
    陈鹏, 李艳超, 黄福军, 等. 方孔障碍物对瓦斯火焰传播影响的实验与大涡模拟 [J]. 爆炸与冲击, 2017, 37(1): 21–26. DOI: 10.11883/1001-1455(2017)01-0021-06.

    CHEN P, LI Y C, HUANG F J, et al. LES approach to premixed methane/air flame propagating in the closed duct with a square-hole obstacle [J]. Explosion and Shock Waves, 2017, 37(1): 21–26. DOI: 10.11883/1001-1455(2017)01-0021-06.
    [7]
    周宁, 王文秀, 张国文, 等. 障碍物对丙烷-空气爆炸火焰加速的影响 [J]. 爆炸与冲击, 2018, 38(5): 1106–1114. DOI: 10.11883/bzycj-2017-0109.

    ZHOU N, WANG W X, ZHANG G W, et al. Effect of obstacles on flame acceleration of propane-air explosion [J]. Explosion and Shock Waves, 2018, 38(5): 1106–1114. DOI: 10.11883/bzycj-2017-0109.
    [8]
    ZHANG P P, ZHOU Y H, CAO X Y, et al. Mitigation of methane/air explosion in a closed vessel by ultrafine water fog [J]. Safety Science, 2014, 62: 1–7. DOI: 10.1016/j.ssci.2013.07.027.
    [9]
    ADIGA K C, HATCHER JR R F, SHEINSON R S, et al. A computational and experimental study of ultra fine water mist as a total flooding agent [J]. Fire Safety Journal, 2007, 42(2): 150–160. DOI: 10.1016/j.firesaf.2006.08.010.
    [10]
    PEI B, YU M G, CHEN L W, et al. Experimental study on the synergistic inhibition effect of nitrogen and ultrafine water mist on gas explosion in a vented duct [J]. Journal of Loss Prevention in the Process Industries, 2016, 40: 546–553. DOI: 10.1016/j.jlp.2016.02.005.
    [11]
    XU H L, LI Y, ZHU P, et al. Experimental study on the mitigation via an ultra-fine water mist of methane/coal dust mixture explosions in the presence of obstacles [J]. Journal of Loss Prevention in the Process Industries, 2013, 26(4): 815–820. DOI: 10.1016/j.jlp.2013.02.014.
    [12]
    ZHU C J, LIN B Q, JIANG B Y, et al. Numerical simulation of blast wave oscillation effects on a premixed methane/air explosion in closed-end ducts [J]. Journal of Loss Prevention in the Process Industries, 2013, 26(4): 851–861. DOI: 10.1016/j.jlp.2013.02.013.
    [13]
    ZHOU Y H, BI M S, QI F. Experimental research into effects of obstacle on methane-coal dust hybrid explosion [J]. Journal of Loss Prevention in the Process Industries, 2012, 25(1): 127–130. DOI: 10.1016/j.jlp.2011.07.003.
    [14]
    BATTERSBY P N, AVERILL A F, INGRAM J M, et al. Suppression of hydrogen-oxygen-nitrogen explosions by fine water mist: Part 2: mitigation of vented deflagrations [J]. International Journal of Hydrogen Energ, 2012, 37(24): 19258–19267. DOI: 10.1016/j.ijhydene.2012.10.029.
    [15]
    裴蓓, 韦双明, 陈立伟, 等. CO2-超细水雾对CH4/air初期爆炸特性的影响 [J]. 爆炸与冲击, 2019, 39(2): 025402. DOI: 10.11883/bzycj-2018-0147.

    PEI B, WEI S M, CHEN L W, et al. Effect of CO2-ultrafine water mist on initial explosion characteristics of CH4/air [J]. Explosion and Shock Waves, 2019, 39(2): 025402. DOI: 10.11883/bzycj-2018-0147.
    [16]
    纪虹, 杨克, 黄维秋, 等. 超细水雾协同甲烷氧化菌降解与抑制甲烷爆炸的实验研究 [J]. 化工学报, 2017, 68(11): 4461–4468. DOI: 10.11949/j.issn.0438-1157.20170568.

    JI H, YANG K, HUANG W Q, et al. Methane degradation and explosion inhibition by using ultrafine water mist containing methane oxidative bacteria-inorganic salt [J]. CIESC Journal, 2017, 68(11): 4461–4468. DOI: 10.11949/j.issn.0438-1157.20170568.
    [17]
    GU R, WANG X S, XU H L. Experimental study on suppression of methane explosion with ultra-fine water mist [J]. Fire Safety Science, 2010, 19(2): 51–59. DOI: 10.3969/j.issn.1004-5309.2010.02.001.
    [18]
    MODAK A U, ABBUD-MADRID A, DELPLANQUE J P, et al. The effect of mono-dispersed water mist on the suppression of laminar premixed hydrogen-, methane-, and propane-air flames [J]. Combustion and Flame, 2006, 144(1−2): 103–111. DOI: 10.1016/j.combustflame.2005.07.003.
    [19]
    杨克, 纪虹, 邢志祥, 等. 含草酸钾的超细水雾抑制甲烷爆炸的特性 [J]. 化工学报, 2018, 69(12): 5359–5369. DOI: 10.11949/j.issn.0438-1157.20180671.

    YANG K, JI H, XING Z X, et al. Characteristics on methane explosion suppression by ultrafine water mist containing potassium oxalate [J]. CIESC Journal, 2018, 69(12): 5359–5369. DOI: 10.11949/j.issn.0438-1157.20180671.
    [20]
    JOSEPH P, NICHOLS E, NOVOZHILOV V. A comparative study of the effects of chemical additives on the suppression efficiency of water mist [J]. Fire Safety Journal, 2013, 58: 221–225. DOI: 10.1016/j.firesaf.2013.03.003.
    [21]
    余明高, 安安, 赵万里, 等. 含添加剂细水雾抑制瓦斯爆炸有效性试验研究 [J]. 安全与环境学报, 2011, 11(4): 149–153. DOI: 10.3969/j.issn.1009-6094.2011.04.034.

    YU M G, AN A, ZHAO W L, et al. On the inhibiting effectiveness of the water mist with additives to the gas explosion [J]. Journal of Safety and Environment, 2011, 11(4): 149–153. DOI: 10.3969/j.issn.1009-6094.2011.04.034.
    [22]
    余明高, 杨勇, 裴蓓, 等. N2双流体细水雾抑制管道瓦斯爆炸实验研究 [J]. 爆炸与冲击, 2017, 37(2): 194–200. DOI: 10.11883/1001-1455(2017)02-0194-07.

    YU M G, YANG Y, PEI B, et al. Experimental study of methane explosion suppression by nitrogen twin-fluid water mist [J]. Explosion and Shock Waves, 2017, 37(2): 194–200. DOI: 10.11883/1001-1455(2017)02-0194-07.
    [23]
    GAN B, LI B, JIANG H P, et al. Suppression of polymethyl methacrylate dust explosion by ultrafine water mist/additives [J]. Journal of Hazardous Materials, 2018, 351: 346–355. DOI: 10.1016/j.jhazmat.2018.03.017.
    [24]
    陈晓坤, 林滢, 罗振敏, 等. 水系抑制剂控制瓦斯爆炸的实验研究 [J]. 煤炭学报, 2006, 31(5): 603–606. DOI: 10.3321/j.issn:0253-9993.2006.05.012.

    CHEN X K, LIN Y, LUO Z M, et al. Experiment study on controlling gas explosion by water-depressant [J]. Journal of China Coal Society, 2006, 31(5): 603–606. DOI: 10.3321/j.issn:0253-9993.2006.05.012.
    [25]
    CAO X Y, REN J J, BI M S, et al. Experimental research on the characteristics of methane/air explosion affected by ultrafine water mist [J]. Journal of Hazardous Materials, 2017, 324: 489–497. DOI: 10.1016/j.jhazmat.2016.11.017.
    [26]
    CAO X Y, REN J J, ZHOU Y H, et al. Suppression of methane/air explosion by ultrafine water mist containing sodium chloride additive [J]. Journal of Hazardous Materials, 2015, 285: 311–318. DOI: 10.1016/j.jhazmat.2014.11.016.
    [27]
    CAO X Y, REN J J, BI M S, et al. Experimental research on methane/air explosion inhibition using ultrafine water mist containing additive [J]. Journal of Loss Prevention in the Process Industries, 2016, 43: 352–360. DOI: 10.1016/j.jlp.2016.06.012.
    [28]
    NFPA. NFPA 750 Standard for the installation of water mist fire protection systems [S]. Quincy, MA: National Fire Protection Association, 2000.
    [29]
    秦俊, 廖光煊, 王喜世, 等. 细水雾抑制火旋风的实验研究 [J]. 自然灾害学报, 2002, 11: 60–65. DOI: 10.3969/j.issn.1004-4574.2002.04.010.

    QIN J, LIAO G X, WANG X S, et al. Experimental study on extinguishment of fire whirlwind by water mist [J]. Journal of Natural Disasters, 2002, 11: 60–65. DOI: 10.3969/j.issn.1004-4574.2002.04.010.
    [30]
    AKIRA Y, TOICHIRO O, WATARU E, et al. Experimental and numerical investigation of flame speed retardation by water mist [J]. Combustion and Flame, 2015, 162: 1772–1777. DOI: 10.1016/j.combustflame.2014.11.038.
    [31]
    邓军, 田志辉, 罗振敏, 等. Mg(OH)2/CO2抑爆瓦斯实验研究 [J]. 煤矿安全, 2013, 44: 4–6. DOI: 10.13347/j.cnki.mkaq.2013.10.014.

    DENG J, TIAN Z H, LUO Z M, et al. Experimental research on suppressing gas explosion by Mg(OH)2/CO2 [J]. Safety in Coal Mines, 2013, 44: 4–6. DOI: 10.13347/j.cnki.mkaq.2013.10.014.
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